
Bohr’s
Postulates
In order to
explain the stability of the atom and line spectra. Bohr suggest a set of Postulates
1. An electron In an atom revolves
around the nucleus in a circular orbit. The force between the electron and the
nucleus provide the necessary centripetal force for the circular motion.
2. The electron revolve in the
certain orbital for which the angular momentum is an integral multiple of h/2Î . the allowed orbitals are given by
mvr= h/2Î …………………(1)
Where
n is an integer (1,2,3,4…………….)
h is Plank constant value of h is
6.6
10-34Js.

This Postulate is known as the
quantization of the angular momentum.
3. The electron moving in an allowed orbit dose
not radiate energy. Therefore the total energy of the electron remain constant
in an allowed orbit in an atom.
4. Electromagnetic radiation is emitted
when the electron jump from high energy orbital to lower energy orbital
The frequency v of
the emitted radiation is given as
Let E1 is
the energy of the higher energy orbital.
And E2 is
the energy of lower energy orbital now the frequency is given by
V=E1-E2/h
……………………..(2)
Equation
(2) represent the Bohr’s frequency condition
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